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Organic Chemistry


Introduction

Organic chemistry, also known as “carbon chemistry”, is chemistry involving organic — or “carbon-based” — molecules. All life on Earth can be considered an expression of complex carbon chemistry. However, since lots of non-living things are carbon-based as well, organic chemistry isn't merely limited to biochemistry. Organic chemistry also deals with polymers, petroleum products, and much more.


Organic Molecule Classes & Functional Groups


Methane

Alkanes & Alkyl Groups — alkane molecules and alkyl functional groups are single-bonded hydrocarbons.
IR Absorption: Medium to strong @ 2850-2975 cm-1



Ethene

Alkenes & Alkenyl Groups — characterized by double-bonds between carbons.
IR Absorption: Medium to weak @ 1640-1680 cm-1 (medium @ 3020-3100 for conjugated alkane-alkene)



Ethyne

Alkynes & Alkynyl Groups — alkyne molecules and functional groups have triple-bonds between carbon atoms.



Chloromethane

Alkyl Halides & Halide Groups — organic halide molecules, also known as halocarbons or alkyl halides, are carbon-based molecules that contain one or more halogens.



Methanol

Alcohols & Hydroxyl Groups — alcohols are molecules that have one or more hydroxyl groups.



Dimethyl Ether

Ethers



Methyl Amine

Amines



Methanethiol

(Organic) Thiols



Dimethyl Sulphide

(Organic) Sulphides



Acetonitrile

Nitriles



Methanal

Aldehydes — the simplest aldehyde is methanal, also known as formaldehyde.



Propanone

Ketones — the simplest ketone is propanone.



Methanoic Acid

Carboxylic Acids — the simplest carboxylic acid is methanoic acid, also known as formic acid.


Molecular Geometry

For more information, see molecular geometry.

Orbital Hybridization — has to do with the angle of bonds to atoms.

Chirality — has to do with the ordering of bonds to atoms.


Conformation

Staggered Conformation — is the stablest conformation for C-C bonds.

Eclipsed Conformation

causes the most steric hindrance.

Chair Conformation — the stablest conformation for cyclohexane rings.

Boat Conformation


Isomerism

For more information, see isomer.


Constitutional Isomers — have the same chemical formula (i.e., the same number of every kind of atom) but are put together in entirely different ways.

Stereoisomers — have the all the same atoms bonded to the same atoms, thus having not only the same constitution but also somewhat similar configuration, however the bonds between some of these atoms are oriented differently.


Ionization & Formal Charge

Carbocation — a carbon with only three bonds and a positive formal charge.

Carbanion — has one lone pair of valence electrons and a negative formal charge.

Free Radical — have a single, unpaired valence electron and a formal charge of zero.


Acids & Bases

For more information, see acids & bases.

Acid Disassociation Constant [Ka] — stronger acids have a larger Ka value.

pKa — negative log of the acid disassociation constant.

Proton Concentration [pH] — a lower pH value indicates greater acidity, while a higher pH value indicates great basicity.

Equilibrium Constant [Keq]


Table of Reactions

Reaction TypeReagentsProducts
AdditionPolarElectrophilicDihalo addition
Hydrohalogenation
Hydrogenation
HydrationHydroboration-OxidationAlkenesAlcohols
Mukaiyama’s Hydration
Oxymercuration
Nucleophilic Addition
Non-PolarFree-radical
Cycloaddition
SubstitutionElectrophilicAromatic
AliphaticNitrosation
Ketone halogenation
Keto-enol tautomerism
NucleophilicUnimolecular [SN1]
Bimolecular [SN2]
Aromatic [SNAr]
Internal [SNI]
EliminationUnimolecular [E1]
Bimolecular [E2]

Regiochemistry

Markovnikov

Stereochemistry

Anti adddition

Syn addition

Erata

Check out this pure HTML periodic table of elements.

Abiogenesis


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