Alkene
Introduction
Alkenes, also known as “olefins”, are hydrocarbons characterized by the presence of at least one double-bond connecting a pair of carbon atoms.
Some Examples of Alkenes
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Ethene [C2H4] — the simplest of alkenes. |
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Propene [C3H6] — |
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Cyclopropene [C3H4] — a constitutional isomer of propadiene. |
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Propadiene [C3H4] — a constitutional isomer of cyclopropene. |
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Isobutene [C4H8] — |
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Cis-2-butene [C4H8] — a geometric isomer of trans-2-butene and a constitutional isomer of isobutene. |
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Trans-2-butene [C4H8] — a geometric isomer of cis-2-butene and a constitutional isomer of isobutene. |
Some Alkene Reactions
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Table of Reactions
Reaction Type | Reagents | Products | ||||
Addition | Polar | Electrophilic | Dihalo addition | |||
Hydrohalogenation | ||||||
Hydrogenation | ||||||
Hydration | Hydroboration-Oxidation | Alkenes | Alcohols | |||
Mukaiyama’s Hydration | ||||||
Oxymercuration | ||||||
Nucleophilic Addition | ||||||
Non-Polar | Free-radical | |||||
Cycloaddition | ||||||
Substitution | Electrophilic | Aromatic | ||||
Aliphatic | Nitrosation | |||||
Ketone halogenation | ||||||
Keto-enol tautomerism | ||||||
Nucleophilic | Unimolecular [SN1] | |||||
Bimolecular [SN2] | ||||||
Aromatic [SNAr] | ||||||
Internal [SNI] | ||||||
Elimination | Unimolecular [E1] | |||||
Bimolecular [E2] |
Regiochemistry
Markovnikov
Stereochemistry
Anti adddition
Syn addition
Erata
Check out this pure HTML periodic table of elements.