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Acids & Bases


Introduction

Vital to the study of chemistry, especially organic chemistry and biochemistry, is understanding acid and base chemistry.

Famous acids include the amino acids.

AcidBase
ArrheniusH+ in H2OOH— in H2O
Bronsted-Lowry[H+] proton donor[H+] proton acceptor
Lewiselectron pair acceptorelectron pair donor

Conjugates

Carbonic acid (H2CO3) reacts with an hydroxide ion (HO-) to produce bicarbonate (HCO-) and water (H2). The carbonic acid becomes bicarbonate as it loses a hydrogen to the hydroxide ion, transforming it into water. The carbonic acid is a proton donator, making it an acid. The hydroxide ion is a proton acceptor, making it a base. The bicarbonate now has one less proton than carbonic acid, making it carbonic acid’s conjugate base. The water has one more proton than the hydroxide ion, making it hydroxide’s conjugate acid.

Important Units & Measurements

[Ka]

Acid Dissociation Constant [Ka] —

[pKa]

–Log Acid Dissociation Constant [pKa] — this number can be used to calculate pH.

[H+]

Proton Concentration —

[pH]

–Log Proton Concentration —

Strong Acids favor Reactants



Acids & Bases
[Ka] [pKa] [H+] [pH]

Thermodynamics
[G] [ΔG] [ΔG°] [ΔG°’] [Keq]

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