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pH


Introduction

The pH scale is a standard measurement system used to indicate acidity with lower numbers and basicity with higher numbers. Pure water has a pH of 7, which is what we tend to think of as “neutral”.


—Log Proton Concentration [pH]

pH is defined as the negative log of the proton concentration.
Substance[H+] concentrationscientific notationpH
lemon juice0.01 mol/L1x10–22
black coffee0.00001 mol/L1x10–55
pure H2O0.0000001 mol/L1x10–77
human blood0.00000004 mol/L1x10–7.47.4
sea water0.00000001 mol/L1x10–88
baking soda0.000000000316227766 mol/L1x10–9.59.5


[H+] from pH

What if you know the pH of a substance, and want to know how that translates to proton concentration?

Just remember:

Knowing this, you can simply plug in your pH as your Y value, allowing X to represent your proton concentration.

Using pure water (pH=7), let’s first take the log positive by shifting the negative to the other side of the equation:

Having done, that, we can simply follow the “if log X = Y, then X = 10Y” logic:

Thus, having run the calculation in reverse, we know that if pure water has a pH of 7, then its proton concentration must be 1x10-7 M.


Henderson-Hasselbalch equation

Another way to calculate pH, which is especially useful for buffer solutions:


Strong Acids favor Reactants



Acids & Bases
[Ka] [pKa] [H+] [pH]

Thermodynamics
[G] [ΔG] [ΔG°] [ΔG°’] [Keq]

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